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Beilstein J. Org. Chem. 2015, 11, 1520–1527, doi:10.3762/bjoc.11.166
Graphical Abstract
Figure 1: Examples of ruthenium complexes used in olefin metathesis reactions.
Scheme 1: Synthesis of the mixed phosphine/phosphite complex 1.
Figure 2: Molecular structure of mixed phosphine/phosphite complex 1. Hydrogen atoms are omitted for clarity.
Scheme 2: Synthesis of the bis-phosphite complex 2.
Figure 3: Molecular structure of 2 and the ylide 3. Hydrogen atoms and solvent molecules are omitted for clar...
Figure 4: Reaction profiles of mixed phosphine/phosphite 1 and phosphine-based Ind-I in the RCM of 4 (lines a...